Search results for "Authigenic carbonate"
showing 3 items of 3 documents
Carbon, iron and sulphur cycling in the sediments of a Mediterranean lagoon (Ghar El Melh, Tunisia)
2019
Coastal lagoon sediments are important for the biogeochemical carbon cycle at the land-ocean transition, as they form hotspots for organic carbon burial, as well as potential sites for authigenic carbonate formation. Here, we employ an early diagenetic model to quantify the coupled redox cycling of carbon, iron and sulphur in the sediments of the shallow Ghar El Melh (GEM) lagoon (Tunisia). The model simulated depth profiles show a good correspondence with available pore water data (dissolved inorganic carbon, NH 4 + , total alkalinity, Ca 2+ , Fe 2+ and SO 4 2− ) and solid phase data (organic matter, pyrite, calcium carbonate and iron (oxyhydr)oxides). This indicates that the model is abl…
Onset of the Messinian Salinity Crisis: Sedimentological, petrographic and geochemical characterization of the pre-salt sediments from a new core (Ca…
2022
The present study aims to reconstruct the environmental changes leading to the Messinian Salinity Crisis during the transition from the Tortonian-Messinian marine conditions to the Messinian evaporitic environments. The core 3AGN2S04, recently drilled in the Caltanissetta Basin (Sicily), was analyzed to reveal the petrographic, mineralogical and geochemical characteristics of the late Tortonian – early Messinian pre-salt sediments. In particular, the facies characterization of the carbonates and organic-rich shales of the Calcare di Base (CdB) member allowed to understand its significance in the paleoenvironmental evolution towards salt deposition and to the reconstruct the brecciation proc…
Formation of secondary carbonates and native sulphur in sulphate-rich Messinian strata, Sicily
2010
Abstract Microbially formed authigenic carbonates accompanied by native sulphur are present in the ‘Calcare Solfifero’ below a thick succession of gypsum deposited during the Messinian salinity crisis in Sicily. We sampled these carbonates and associated sulphur in five former sulphur mines to subject them to a detailed petrographic and geochemical study in order to explore their different modes of formation. Native sulphur formed in conjunction with microbial sulphate reduction, which is reflected in its depletion in 34S (δ34S values as low as − 2‰ vs. V-CDT) and an enrichment of 34S in the residual sulphate (δ34S values as high as + 61‰). The oxidation of organic matter by sulphate reduct…